Essential Reagents for Organic Synthesis

Editor/Author Fuchs, Philip L., Chartette, Andre B. and Rovis, Tomislav et.al
Publication Year: 2016
Publisher: Wiley

ISBN: 978-1-119-27830-6
Category: Science - Biology
Book Status: Pending
Predicted Release Month: Sept 2019
Table of Contents

For each reagent, a concise article provides a brief description of all important reactions for which the reagent is being used, including yields and reaction conditions, an overview of the physical properties of the reagent, its storage conditions, safe handling, laboratory synthesis and purification methods. Advantages and disadvantages of the reagent compared to alternative synthesis methods are also discussed.

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Table of Contents

  • Preface
  • Short Note on InChIs and InChIKeys
  • General Abbreviations
  • B
  • Bis(dibenzylideneacetone)palladium(0)
  • Original Commentary
  • First Update
  • Second Update
  • 9-Borabicyclo[3.3.1]nonane Dimer
  • Original Commentary
  • Boron Trifluoride Etherate
  • N-Bromosuccinimide
  • Original Commentary
  • First Update
  • n-Butyllithium
  • Original Commentary
  • First Update
  • C
  • N,N′-Carbonyl Diimidazole
  • Original Commentary
  • First Update
  • Cerium (IV) Ammonium Nitrate
  • Original Commentary
  • First Update
  • m-Chloroperbenzoic Acid
  • Original Commentary
  • First Update
  • N-Chlorosuccinimide
  • Original Commentary
  • First Update
  • Second Update
  • Chlorotrimethylsilane
  • Original Commentary
  • First Update
  • Chlorotris(triphenylphosphine)-rhodium(I)
  • Original Commentary
  • First Update
  • D
  • (Diacetoxyiodo)benzene
  • Original Commentary
  • First Update
  • Diazomethane
  • Methylation of Heteroatoms
  • Esterification of Carboxylic Acids and Other Acidic Functional Groups
  • Methylation of Alcohols and Other Less Acidic Functional Groups
  • The Arndt–Eistert Synthesis
  • Other Reactions of α-Diazo Ketones Derived from Diazomethane
  • The Vinylogous Wolff Rearrangement
  • Insertions into Aldehyde C–H Bonds
  • Additions to Ketones
  • Cycloadditions with Diazomethane
  • Additions to Electron-Deficient Species
  • Miscellaneous Reactions
  • Related Reagents
  • 2,3-Dichloro-5,6-dicyano-1,4-benzo-quinone
  • Original Commentary
  • First Update
  • Diisobutylaluminum Hydride
  • Original Commentary
  • First Update
  • 4-Dimethylaminopyridine
  • Original Commentary
  • First Update
  • Dimethyldioxirane
  • Original Commentary
  • First Update
  • E
  • 1-Ethyl-3-(3′-dimethylaminopropyl)carbodiimide Hydrochloride
  • Peptide Coupling Reagent
  • Amide Formation
  • Ester Formation
  • Protein Modification
  • Oxidation of Primary Alcohols
  • Miscellaneous Reactions
  • Related Reagents
  • I
  • N-Iodosuccinimide
  • Original Commentary
  • First Update
  • Second Update
  • Iodotrimethylsilane
  • Original Commentary
  • First Update
  • 2-Iodoxybenzoic acid
  • L
  • Lithium Aluminum Hydride
  • Original Commentary
  • First Update
  • Lithium Diisopropylamide1, 2
  • Original Commentary
  • First Update
  • Lithium Naphthalenide
  • Original Commentary
  • M
  • Manganese Dioxide
  • O
  • Osmium Tetroxide
  • First Update
  • Second Update
  • Oxalyl Chloride
  • Original Commentary
  • First Update
  • Oxalyl Chloride–Dimethylformamide
  • Ozone
  • Original Commentary
  • First Update
  • P
  • Pinacolborane
  • Original Commentary
  • First Update
  • Potassium Hexamethyldisilazide
  • Original Commentary
  • First Update
  • Second Update
  • Potassium Monoperoxysulfate
  • Original Commentary
  • First Update
  • Second Update
  • Potassium tert-Butoxide
  • Original Commentary
  • First Update
  • R
  • Ruthenium(II), Tris(2,2′-bipyridine-κN1,κN1′)-, (OC-6-11)-
  • S
  • Samarium(II) Iodide
  • Original Commentary
  • First Update
  • Scandium Trifluoromethanesulfonate
  • Sodium Azide
  • Original Commentary
  • First Update
  • Sodium Borohydride
  • Original Commentary
  • First Update
  • Second Update
  • Sodium Cyanoborohydride
  • Original Commentary
  • First Update
  • Sodium Hexamethyldisilazide
  • Original Commentary
  • First Update
  • Sodium Hydride
  • Original Commentary
  • First Update
  • Sodium Periodate
  • Original Commentary
  • First Update
  • T
  • Tetrabutylammonium Fluoride
  • Original Commentary
  • Tetrakis(triphenylphosphine)palladium(0)
  • Tetra-n-propylammonium Perruthenate
  • Original Commentary
  • First Update
  • p-Toluenesulfonyl Chloride
  • Original Commentary
  • First Update
  • Triethylsilane
  • Original Commentary
  • First Update
  • Trifluoromethanesulfonic Acid
  • Original Commentary
  • First Update
  • Trifluoromethanesulfonic Anhydride
  • Original Commentary
  • First Update
  • Second Update
  • Trimethylsilyl Trifluoromethane sulfonate
  • Original Commentary
  • First Update
  • Trimethylsilyldiazomethane
  • Original Commentary
  • First Update
  • Z
  • Zinc–Acetic Acid
  • List of Contributors